RuCl(p-cymene)[(S,S)-Ts-DPEN]
Synonym: [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
Formula : C31H35ClN2O2RuS
Molecular weight : 636.21 g/mol
CAS-No. : 192139-90-5
Melting point/range: > 175 °C
Form: solid
Storage:
Keep container tightly closed in a dry and well-ventilated place.
Recommended storage temperature 2 - 8 °C
Handle and store under inert gas. Air and moisture sensitive.
Precautions for safe handling:
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures
for preventive fire protection.
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst involved in:
• Asymmetric transfer hydrogenation of imines and ketones
• Intramolecular asymmetric reductive amination
• Tandem hydroformylation / hydrogenation of terminal olefins
Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes
General description
RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines
